Modified Biopolymers as an Alternative to Petroleum-Based Polymers for Soil Modification

ER-200920

Objective

The objectives of this project are to establish the efficacy of scaling up to pilot production of Rhizobium tropici biopolymer, to determine industrial-scale cost information for production, and to perform a comparative performance evaluation of the biopolymer to a petroleum-based polymer. Areas under investigation are the reduction of soil erosion and surface water transport of lead on small arms firing ranges and atmospheric transport of lead associated with fugitive dust emissions on ranges.

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Technology Description

A technique has been developed through which R. tropici-derived biopolymer can be produced in an aerobic bioreactor. The biopolymer is separated from the growth media and derivatized in order to produce a nonreactive (non-crosslinking) material. During this process, the biopolymer can also be functionalized to improve its adsorption of heavy metals. This nonreactive material can then be transported as a low-density, dry solid and applied to the soil using one of two methods. The first method involves mixing the dry biopolymer with water at the site of use, producing a viscous liquid, or gel, which is applied to the soil surface. The second method involves mixing the dry biopolymer into the soil, then applying water. Using either application method, the biopolymer will form a gel within the soil matrix when wetted. With the soil acting as a buffer, the ionic character of the biopolymer salt is neutralized and the biopolymer can begin reacting with itself and the metal constituents of the soil matrix. The reactive, crosslinked biopolymer has a larger molecular weight, a reduced water affinity, and links together the individual soil particles within the biopolymer matrix. The individual soil particles of the amended soil have greatly reduced mobility, significantly reduced hydraulic conductivity, and compressive strength equal to that produced by synthetic polymer amendments. This change in the physical form of the soil on a particle level will result in increased soil strength, reduced air transport, and decreased soil erosion.

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Benefits

A low-density natural material produced in bioreactors and transported in a dry state may provide an alternative to the synthetic, petroleum-based polymers now in use for Department of Defense (DoD) soil amendment applications. If the biopolymeric material is successful at producing equivalent, or enhanced, improvements in soil properties, it could replace petrochemical soil stabilizing formulations. This may reduce concerns surrounding the use of petroleum-based synthetics in a broad-scale application in the environment, reduce the reliance of DoD on petrochemicals, and provide a means for soils that have been stabilized to naturally return to a near original state, albeit over long periods of time, through biodegradation of the natural biopolymer. (Anticipated Project Completion - 2012)

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Project Documents

Points of Contact

Principal Investigator

Dr. Steven Larson

U.S. Army Engineer Research and Development Center (ERDC)

Phone: 601-634-3431

Fax: 601-634-2742

Program Manager

Environmental Restoration

SERDP and ESTCP

Project Documents

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.