Use of Compound-Specific Stable Isotope Analysis to Distinguish Between Vapor Intrusion and Indoor Sources of VOCs

ER-201025

Objective

The USEPA is increasingly relying on indoor air testing as a primary tool for the evaluation of vapor intrusion.  However, when testing indoor air, distinguishing between vapor intrusion and indoor sources of volatile organic compounds (VOCs) is a significant challenge, greatly increasing the cost and complexity of investigations. The objective of this project is to validate the application of compound-specific stable isotope analysis (CSIA) as a tool to distinguish between vapor intrusion and indoor sources of VOCs. Specific objectives are to:

  • Validate the use of active sorbent samplers for the collection of vapor-phase samples for carbon, chlorine, and hydrogen CSIA of VOCs such as tetrachloroethene (PCE), trichloroethene (TCE), and benzene that commonly drive vapor intrusion investigations
  • Develop a protocol for application of CSIA for vapor intrusion investigationsCharacterize the stable isotope signatures for common indoor VOCs
  • Characterize the stable isotope signatures of subsurface sources of VOCs and the variability in these signatures in close proximity to potentially affected buildings
  • Develop a protocol for application of CSIA to distinguish between vapor intrusion and indoor sources of VOCs
  • Demonstrate CSIA for vapor intrusion investigations by applying the protocol at four buildings (from two different Department of Defense facilities) potentially affected by vapor intrusion.

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Technology Description

CSIA is a proven laboratory analytical method to measure the ratio of stable isotopes (e.g., 13C/12C; 37Cl/35Cl; D/H) in individual chemicals present in environmental samples. Differences in the isotopic ratios between environmental samples can be used to distinguish between different sources of environmental contaminants and understand biodegradation and other transformation processes occurring in the environment. CSIA has been validated and accepted as an effective tool for distinguishing between different sources of VOCs in groundwater. This project will validate the use of CSIA to distinguish between vapor intrusion and indoor sources of VOCs, a novel application of this technology.

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Benefits

When indoor air testing is conducted, VOCs are commonly detected at concentrations above the applicable indoor air screening criteria. Such results often require extensive follow-up testing programs to definitively identify the source of the detected VOCs (i.e., vapor intrusion versus indoor sources). At Hill Air Force Base, for example, more than 25% of the TCE detections above action levels in indoor air have subsequently been attributed to indoor sources of VOCs rather than vapor intrusion. For PCE and 1,2-dichloroethane (1,2-DCA), indoor sources have resulted in even higher percentages of action level exceedances. However, identification of the indoor VOC source has typically required multiple rounds of sampling and analysis, and in many cases an indoor source is identified only after a vapor intrusion mitigation system has been installed and has failed to improve indoor air quality. Validation of CSIA as a method to distinguish between vapor intrusion and indoor sources of VOCs will significantly reduce the effort and cost of testing indoor air at vapor intrusion sites. The development of a validated procedure for use of CSIA to distinguish between vapor intrusion and indoor sources of VOCs could reduce vapor intrusion investigation costs 25% to 50% by significantly reducing the need for follow-up investigation at buildings with exceedances of indoor air screening levels attributable to indoor sources of VOCs. (Anticipated Project Completion - 2013)

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Points of Contact

Principal Investigator

Dr. Thomas McHugh

GSI Environmental Inc.

Phone: 713-522-6300

Fax: 713-522-8010

Program Manager

Environmental Restoration

SERDP and ESTCP

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.