Full-Scale Fixed-Bed Biological Perchlorate Destruction Demonstration

ER-201169

Objective

The objective of this project is to evaluate the efficacy of using fixed-bed (FXB) biological treatment plus post-treatment to remove perchlorate from groundwater and produce water that meets all drinking water standards.

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Technology Description

Bacteria can gain substantial energy by mediating the transfer of electrons from an electron donor (e.g., acetic acid) to an electron acceptor (e.g., perchlorate). Biological perchlorate treatment processes capitalize on this principle by maintaining an environment that fosters the growth of perchlorate-reducing bacteria (PRB). FXB biological processes utilize a stationary bed of media such as sand, plastic, or granular activated carbons (GAC) on which biofilms containing PRB develop. Water is drawn from a well, amended with an electron donor and phosphorus, and then pumped across the media bed. Bacteria in the bed reduce dissolved oxygen, nitrate, and perchlorate. Contacting virgin media with raw water for about a month provides the necessary perchlorate-reducing biological activity, thereby eliminating the need for a perchlorate-reducing inoculum. Effluent from the FXB bioreactor passes through an aeration tank to remove nitrogen gas and add oxygen to the process stream. A low dose of cationic polymer will be added to the aeration tank effluent (condition sloughed biomass for improved filtration), which will then pass through a dual media filter (turbidity removal, residual acetic acid oxidation, hydrogen sulfide oxidation), prior to final disinfection. The FXB bioreactors and polishing filters will be backwashed approximately every 24-26 hours to remove excess biomass. Backwash wastewater will be treated in a dissolved air flotation process to separate the biomass from process water. The process water could then be returned to the head of the plant or discharged to a local sewer or catch basin.

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Benefits

This project represents the first full-scale FXB biological perchlorate treatment process applied to drinking water. As such, it provides a critical step toward wide-scale application of this non-proprietary treatment process. The FXB process is expected to be simple, efficient, robust, and cost-competitive with alternative perchlorate removal technologies. (Anticipated Project Completion - 2014)

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Points of Contact

Principal Investigator

Dr. Jess Brown

Carollo Engineers

Phone: 941-371-9832

Fax: 941-371-9873

Program Manager

Environmental Restoration

SERDP and ESTCP

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.