Cost-Effective, Ultra-Sensitive Groundwater Monitoring for Site Remediation and Management

ER-201122

Objective

Groundwater monitoring at hazardous waste sites is a critical but costly component of site remediation. Unfortunately, the data generated frequently are of limited quality and involve generation of hazardous waste. The objective of this project is to validate a novel in situ sampling (IS2) technology that can provide the Department of Defense (DoD) and other remediation stakeholders with better data at a reduced cost, using an environmentally sound sampling approach that limits the generation of hazardous waste during sample acquisition, processing, and analysis. Specific contaminants to be investigated include volatile organic compounds, explosives, semivolatile compounds, polycyclic aromatic hydrocarbons, inorganic water contaminants, and heavy metals. These analytes will be captured and concentrated in situ, using two separate IS2 devices. One is designed to fit into a standard groundwater monitoring well measuring 4 inches in inner diameter, and the other is sized to fit into a 2-inch well. Performance of the two devices and their automated downstream analysis strategy will be demonstrated in laboratory experiments and in multiple deployments at DoD sites, using conventional water monitoring data as a benchmark for direct comparison.

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Technology Description

The IS2 is a sentinel technology and innovative tool for monitoring contaminants in groundwater. This active sampling device is deployed downhole in a monitoring well, where its integrated pumps draw ambient groundwater at mL/day rates and contact the stream of water with solid adsorption media on which analytes of interest become concentrated over time. The effluent of the device remains in the subsurface, and only the device with the extracted analytes is retrieved. As a result, use of the device produces zero purge water and zero wastewater at the surface. Contaminant-charged extraction media are shipped to the laboratory where they get processed in an automated analysis strategy using robotics and standard analytical detection strategies, such as mass spectrometry or ion chromatography. Hallmarks of the technology are ultra-low detection limits in the ng/L and pg/L range, zero production of wastewater, and low per-sample costs due to a high degree of automation.

This project will demonstrate the applicability of the IS2 technology to monitoring DoD priority pollutants in groundwater. Results from deployment of the IS2 technology will be directly compared to data obtained concomitantly by DoD contract laboratories using contemporary approaches. Metrics of success for this project include method detection limits 10- to 100-times lower than those of Environmental Protection Agency (EPA) methods; accuracy, precision, and reproducibility of IS2 analysis matching or exceeding those of EPA methods; spectrum of compounds amenable to IS2 analysis; sample holding time and required temperature; volume of hazardous waste generated; and cost per sample processed.

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Benefits

Principal advantages of the IS2 technology over conventional groundwater monitoring are its low costs, the ability to contour contaminant plumes at heretofore unattainably low concentrations, the acquisition of time-integrated measurements, and avoidance of hazardous waste. Use of the IS2 sentinel technology by DoD and other remediation stakeholders is projected to lead to superior data, a reduction in carbon and energy requirements, and significant cost savings. (Anticipated Project Completion - 2014)

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Points of Contact

Principal Investigator

Dr. Rolf Halden

Arizona State University

Phone: 480-727-0893

Program Manager

Environmental Restoration

SERDP and ESTCP

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.