The Effect of Soil Properties on Decreasing Toxic Metal Bioavailability: Field Scale Validation to Support Regulatory Acceptance
ER-200517
Objective
The Department of Defense (DoD) faces a potentially daunting task of remediating thousands of metal-contaminated sites. With the exception of lead, human health and ecological risk drivers have prompted the U.S. Environmental Protection Agency to assume that the total soil metal concentration is 100% bioavailable. Previous research, however, has shown that the ubiquitous metal-sequestering properties of soil can significantly lower the bioavailability and risk of toxic metals. This project seeks to obtain regulatory acceptance of in vitro methods and the Soil BioAccessibility Tool (SBAT) for assessing toxic metal bioavailability in DoD soils.
Technology Description
By quantifying the extent that soil properties control metal bioavailability, researchers will show that the models developed in SERDP projects ER-1166 and ER-1210 can be used with a reasonable level of confidence to predict site-specific metal bioavailability for DoD soils throughout the United States. The chemical speciation, bioaccessibility, bioavailability, and toxicity of lead, arsenic, cadmium, chromium in soils from DoD sites to biological receptors used to evaluate ecological risk (e.g., plants, earthworms) and human risk (e.g., immature swine model) will be determined to validate the SBAT. Researchers also will show that in vitro methods can be used for risk assessment of toxic metals in soil by comparing in vitro and in vivo metal bioavailability studies. The in vitro ecological models will be enhanced by considering approximately ten DoD soils for in vivo ecological bioassay studies (10 contaminated, 10 control) that have already been screened using the Physiologically Based Extraction Test (PBET). In an effort to advance complete or partial acceptance of in vitro methods in human health and ecological risk assessment and policy, this project will bring together regulators, end-users, and scientists to discuss the research strategy and demonstrate the applicability of these concepts. Additional information is available at http://www.esd.ornl.gov/research/earth_sciences/estcp.shtml.
Benefits
Results from this project will provide site managers and risk assessors with tools to make better initial estimates of risk. These risk estimates can be used to prioritize sites and to justify more definitive site-specific in vivo bioavailability studies. Measures of metal bioavailability also can be used to eliminate sites or portions of sites from further risk assessment procedures during screening or Phase I procedures. In vitro methods will help focus prudent use of limited fiscal resources for contaminant remediation and cleanup on DoD sites. Regulatory acceptance of in vitro methods will produce cost savings in the range of billions of dollars.
Points of Contact
Principal Investigator
Ms. Amy Hawkins
Naval Facilities Engineering Command Engineering Service Center
Phone: 805-982-4890
Fax: 805-982-4304
Document Types
- Fact Sheet - Brief project summary with links to related documents and points of contact.
- Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
- Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
- Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
- Guidance - Instructional information on technical topics such as protocols and user’s guides.
- Workshop Report - Summary of workshop discussion and findings.
- Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
- Model/Software - Computer programs and applications available for download.
- Database - Digitally organized collection of data available to search and access.
