Elimination of Perchlorate Oxidizers from Pyrotechnic Flare Compositions

WP-200730

Objective

The objective of this project is to qualify and introduce into service inventories improved perchlorate-free pyrotechnic compositions for colored signal flares. The new compositions substitute alternate oxidizers such as metal nitrates and produce equal or superior emission intensities in the appropriate spectral regions. Since these nonperchlorate oxidizers are typically less reactive and energetic than the perchlorates, various ultrafine and high energy metal fuels and alloys are used to make up for this energy shortfall.

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Technology Description

During SERDP-funded laboratory-scale testing (WP-1280), three promising perchlorate-free red flare compositions designated RSF-2A, RSF-2B, and RSF-2C were identified. In recent prototype-scale testing, the RSF-2C composition with a combination of magnesium and magnalium alloy fuels and strontium nitrate and calcium nitrate oxidizers most closely approached the performance of the in-service, perchlorate-containing Mk 124, Red, Marine Smoke and Illumination Signal composition. However, the highly hygroscopic calcium nitrate ingredient seemed to be causing variable levels of degradative aging that were adversely affecting performance parameters such as candle power intensity and burn rate. Most recently, the performance of a fourth perchlorate-free red candidate that contains no calcium nitrate or potassium perchlorate oxidizers has been tested. It is quite similar to the composition used in the Army M158 Ground Illumination Signal, Red Star Cluster, with the exception of the detailed particle size distribution of the magnesium fuel, which has been fine-tuned to produce a burn rate similar to the in-service Mk 124 flare. It appears to consistently provide equal or superior burn rate, candle power intensity, dominant wavelength, and color purity performance when compared with the in-service Mk 124 red flare composition. The formulation qualification, final type qualification, and technical evaluation testing of the perchlorate-free red flare represent the thrust of this project.

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Benefits

The new perchlorate-free pyrotechnic flare compositions will eliminate the adverse impact to the environment of perchlorate contamination during manufacturing and testing operations. Elimination of the perchlorates from these compositions also will lead to a reduction in future cleanup costs of military facilities contaminated by perchlorate during the life cycle of the flares. Having environmentally acceptable colored signal flares available in the service inventories will avoid disruptions in training schedules as the U.S. Environmental Protection Agency and individual states continue to promulgate restrictive limits on perchlorate contamination in groundwater.

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Points of Contact

Principal Investigator

Ms. Christina Yamamoto

Naval Surface Warfare Center - Crane

Phone: 812-854-2044

Fax: 812-854-4065

Program Manager

Weapons Systems and Platforms

SERDP and ESTCP

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.