Microstructurally Adaptive Constitutive Relations and Reliability Assessment Protocols for Lead Free Solder

WP-1752

Objective

Legislation has banned the use of lead in solder for the vast majority of microelectronics products, and the complete switch of the consumer industry to lead-free soldering makes an eventual transition by Department of Defense (DoD) suppliers inevitable. However, the necessary quantitative understanding of long-term reliability effects is still missing. The properties of common lead-free solder joints are fundamentally different from those of tin-lead (SnPb). Prediction of the life of lead-free solder joints under even the simplest long-term service conditions cannot be done following current accelerated test protocols or modifying parameters in current models or expressions for SnPb. Quantitative predictions of long-term life under conditions of vibration, shock, and thermal excursions may be off by orders of magnitude. Even qualitative comparisons of alternative lead-free materials, design, or process options can be misleading. Also, indications are that the damage done in environmental stress screening (ESS) may be seriously underestimated. The issue is furthur complicated by the ongoing evolution of solder properties over the entire life, including interactions with solder volume and pad size, pad finishes, and reflow profile, as well as with subsequent thermal and loading history. In addition, suppliers continue to develop new alloys and users have to count on having to deal with numerous combinations of these in a single assembly. While consequences for consumer electronics are negligible or absent, the potential safety repercussions in certain military and aerospace applications may be incalculable.

The objective of this project is to develop a quantitative knowledge and understanding of lead-free solder joints as well as lead-free joints mixed with SnPb. Based on this knowledge, researchers will define test protocols and guidelines for the interpretation of test results in terms of life in long-term service.

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Technical Approach

The properties of lead-free solder joints under any kind of loading are determined by their microstructure and composition. Both will be characterized under a comprehensive range of conditions using a carefully selected combination of tests, some of them developed in the principal investigators' laboratories to extract very specific quantitative information about microstructure-property correlations. The resulting quantitative mechanistic understanding of the property evolution in processing, test, and service will allow the development of microstructurally adaptive constitutive laws for solder deformation and damage. These laws self-adjust with in situ changes in microstructure during storage and service to enable reliable predictions of deformation and damage. An innovative aspect of this project is the use of model-based approaches to develop a mechanistic understanding of microstructural effects on thermomechanical behavior. By providing a quantitative assessment of the relative importance of various microstructural effects on deformation and damage, the model-based approach will provide a framework for a knowledge-based approach to developing accelerated test protocols.

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Benefits

Benefits to DoD users and the scientific community will include the identification of critical parameters to be controlled and practical tools for the prediction and assessment of the life of lead-free solder joints under a broad range of potential service conditions. This will include accounting for factors only of concern under long-term service conditions such as those encountered in many DoD applications. (Anticipated Project Completion - 2013)

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Points of Contact

Principal Investigator

Dr. Peter Borgesen

Binghamton University

Phone: 607-768-2132

Program Manager

Weapons Systems and Platforms

SERDP and ESTCP

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.