The Science of Emissions from Alternative Fuels

WP-2145

Objective

Engine companies use computational fluid dynamics (CFD) and empirical models to design low emissions gas turbine combustors (GTCs) burning JP-8 fuel. The models do a good job in estimating emissions trends for different GTC designs, but, for some emissions such as non-volatile PM2.5 (soot) and hazardous air pollutants (HAPs), the errors are so large they are not usually calculated. It is difficult to identify and focus on the cause of the errors because of the strong coupling between the chemical and physical (e.g., turbulence, fuel vaporization) processes, and the results published by independent researchers cannot be readily integrated into a uniform theory because of mismatched experimental conditions. These problems have been successfully addressed following a new approach in a SERDP soot science project (WP-1577). This approach has been so successful that a transition to a soot design model for JP-8 fuel could start in 2011. A similar approach could be used to establish a science base for alternative fuels that can lead to emissions design models and a methodology for selecting—or limiting—future alternative fuels.

The objectives of this project are to: (1) establish the science base needed to develop accurate models for total unburned hydrocarbons (UHC), HAPs, non-volatile particulate emissions (PM), carbon monoxide (CO), and oxides of nitrogen (NOx) emissions from military gas turbine engines burning alternative fuels, and (2) establish a science-based methodology for selecting practical alternative fuels that minimize emissions.

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Technical Approach

This project will focus on understanding the fundamental effects of chemistry and physical properties of alternative fuels on all emissions, with a special emphasis on HAPs. Researchers will use a suite of burners to conduct a series of experiments designed to progress in complexity in ways that allow systematic analysis and interpretation of the data. A proven CFD code (UNICORN), with full chemistry and emissions mechanisms, will be used to evaluate the fuel chemistry/emissions models and to interpret the experimental results. During the last year of the project, the capabilities of the fuel chemistry/emissions models will be demonstrated using a single swirl-cup rig that is anticipated to be used on the Air Force (AF) Alternative Rules and Tools program with the engine companies. The selection of alternative fuels will be aided by studies conducted on another AF program, using a special alternative fuels processing facility. Surrogates for the selected alternative fuels will be formulated based on the procedures established by the Air Force Office of Scientific Research (AFOSR) Fuels Multidisciplinary Research Program of the University Research Initiative (MURI) and the availability of full chemistry models.

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Benefits

As the Department of Defense and the nation move toward a sustainable energy base, this project will provide modeling tools that can be used to design GTCs for low pollutant emissions, high performance gas turbines burning alternative fuels and a methodology for evaluating emissions from future alternative fuels. (Anticipated Project Completion - 2016)

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Points of Contact

Principal Investigator

Dr. Mel Roquemore

Air Force Research Laboratory

Phone: 937-255-6813

Fax: 937-656-4570

Program Manager

Weapons Systems and Platforms

SERDP and ESTCP

Document Types

  • Fact Sheet - Brief project summary with links to related documents and points of contact.
  • Final Report - Comprehensive report for every completed SERDP and ESTCP project that contains all technical results.
  • Cost & Performance Report - Overview of ESTCP demonstration activities, results, and conclusions, standardized to facilitate implementation decisions.
  • Technical Report - Additional interim reports, laboratory reports, demonstration reports, and technology survey reports.
  • Guidance - Instructional information on technical topics such as protocols and user’s guides.
  • Workshop Report - Summary of workshop discussion and findings.
  • Multimedia - On demand videos, animations, and webcasts highlighting featured initiatives or technologies.
  • Model/Software - Computer programs and applications available for download.
  • Database - Digitally organized collection of data available to search and access.